Product ID:1601 GLOSSY BLACK, INDUSTRIAL MAINTENANCE (SUPDAT)
MSDS Date:09/01/1996
FSC:8010
NIIN:00-132-2863
Status Code:A
MSDS Number: CJCKX

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 215-566-2917

Info Phone: 800-777-2966

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 8%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

7.1.

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 70%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.5.

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: 11-30%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM, S, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

180.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 35%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM; 1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

70.

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 12%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM; 300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1.8.

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 11%

OSHA PEL N/K

ACGIH TLV: N/K

VOLATILE ORGANIC COMPOUND BY WEIGHT PER BAAQMD RULE 49

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

THESE PRODS CNTN CHEM/S KNOWN TO STATE OF

RTECS: 9999999ZZ

NOT INCINERATE. DEPRESSURIZE CNTNR.

RTECS: 9999999ZZ

VENTD - DO NOT SMOKE - EXTING ALL FLAMES,

RTECS: 9999999ZZ

& APPLIANCES & ANY OTHER IGNIT SOURCES. CONSULT NFPA

RTECS: 9999999ZZ

UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO

RTECS: 9999999ZZ

WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO

RTECS: 9999999ZZ

LISTED "AS DUST" IN INGRED SECTION) WHICH MAY

RTECS: 9999999ZZ

OF DRIED FILM. IF NO SPECIFIC DUSTS LISTED, APPLIC

RTECS: 9999999ZZ

(TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3

RTECS: 9999999ZZ

FROM THIS PRODUCT, UNDERLYING PAINT OR THE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE EXPOS TO VAPS OR SPR AY MISTS. REDNESS & ITCHING OR
BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS.
CHRONIC: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PRLNGD OVEREXP TO SOLVENT INGREDS
LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING,
CARDIOVASCULAR & REPRO SYSTEMS. METHYL ETHYL KETONE MAY INCR
NERVOUS SYSTEM EFTS OF OTHER SO LVENTS. REPORTS HAVE ASSOC RPTD &
PRLNGD OVEREXP TO SOLVENTS W/PERM BRAIN & NERVOUS SYSTEM DAMAGE.
WARNING: (ING 10)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP
WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER.
REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH EYES
W/LARGE AMT S OF WATER FOR AT LEAST 15 MIN. GET MEDATTN. INGEST:
NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. DO NOT INDUCE
VOMITING. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED
ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP
OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE
& UNTIL ALL VAPS ARE GONE - KEEP AREA (ING 12)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. THIS COATING MAY CNTN MATLS CLASSIFIED AS
NUISANCE PARTICULATES LISTED "AS DUST" IN INGRED SECTION WHICH MAY
CONTAIN MATLS CLASS IFIED AS NUISANCE PARTICULATES (ING 16)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR NIOSH APPRVD, PROPERLY FITTED ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED
(ING 19)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.84, 107, 108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:USE ONLY W/ADEQUATE VENT. AVOID BREATHING VAPOR
& SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: & TOUCH UP SPRAY COLORS. FIRE FIGHT PROC: TO
PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO
EXTREME HEAT. EXPLO HAZ: SURFS REQS SPEC PRECS. DURING EMER CNDTNS
OVEREXP TO DECOMP PRODS MAY CAUSE A HEALTH HAZ. SYMPS MAY NOT BE
IMMED APPARENT. OBTAIN MED ATTN.

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.76
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING METHYL
ETHYL KETONE OR COPPE R MAY REQ TESTING FOR EXTRACTABILITY. DO (ING
11)

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.